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Carbon monoxide CO mwepụ ihe na-akpali akpali nwere Noble metal

Carbon monoxide CO mwepụ ihe na-akpali akpali nwere Noble metal

nkowa nkenke:

Carbon monoxide CO mwepụ ihe mkpali nke Xintan na-emepụta bụ ezigbo metal catalyst (palladium) dabeere na alumina ụgbọelu catalyst, eji wepụ H2 na CO na CO2 na 160 ℃ ~ 300 ℃.Ọ nwere ike tọghata CO n'ime CO2 na tọghata H2 n'ime H2O.Ọ naghị agụnye MnO2, CuO ma ọ bụ sọlfọ, ya mere enwere ike iji ya mee ihe n'enweghị ihe ọ bụla maka ịdị ọcha CO na CO2, nke a na-ejikarị eme ihe maka ụlọ ọrụ nri.
N'okpuru ebe a bụ isi ọnọdụ maka nke a dị oké ọnụ ahịa metal catalyst.
1) mkpokọta sọlfọ ọdịnaya≤0.1PPM.(nke isi ihe)
2) mmeghachi omume nrụgide <10.0Mpa, mmalite adiabatic reactor mbata okpomọkụ bụ n'ozuzu 160 ~ 300 ℃.


Nkọwa ngwaahịa

Mkpado ngwaahịa

paramita ngwaahịa

Efrata AlO na palladium (Pd)
Ụdị gburugburu
Nha Dayameta: 3mm-5mm
Nnukwu njupụta 0 .70 ~ 0 .80g/ml
Mpaghara elu 170m2/g
GHSV 2.0 ~ 5.0 × 103
Mmeghachi omume nke ọdịnaya CO na ọdụ gas 1 ppm
Ọnọdụ okpomọkụ na-arụ ọrụ 160-300 ℃
Ndụ ọrụ 2-3 afọ
Nrụgide arụ ọrụ 10.0Mpa
Oke ibu nke ịdị elu na dayameta 3:1

Usoro iji gbakọọ ọnụọgụ achọrọ

A) Dabere na CO na H2 ịta, ikuku na-arụ ọrụ okpomọkụ na iru ala.
B) Mpịakọta nke ihe na-akpali akpali = Ikuku ikuku/GHSV.
C) Ibu nke ihe mkpali = Olu * nnukwu ike ndọda (oke njupụta)
D) Xintan nwere ike inye ndụmọdụ ndị ọkachamara gbasara oke achọrọ

Atụmatụ nbudata

Mbelata nrụgide nke akwa akwa na ụlọ ọrụ mmepụta ihe nwere njikọ chiri anya na nha nke ịdị elu na dayameta nke ihe ndina, nha nke ikuku gas, porosity nke efere nkesa gas , ọdịdị na nha nke ihe na-emepụta ihe, ike ọrụ na arụ ọrụ. usoro ọnọdụ.Dịka ahụmịhe anyị siri dị, a na-achịkwa oke ịdị elu na dayameta nke akwa akwa na ihe dịka 3: 1.

Lezienụ anya na mmetụta nke afụ na alụlụ acid mgbe ị na-eji ma na-echekwa ihe mkpali.Mgbe ị na-ejuputa, buru ụzọ dọba akwa akwa nke igwe anaghị agba nchara (oghere bụ 2.5 ~ 3mm), wee tinye akwa akwa nke ihe dịka 10cm ceramic ball (Ø10 ~ 15mm);A na-etinye akwa akwa nke igwe anaghị agba nchara n'elu akụkụ elu nke oyi akwa seramiiki dị ka nkwado nke ihe ndina, mgbe ahụ, a na-ebu ihe na-emepụta ihe.Mgbe ị na-ebu ibu, ndị ọrụ dị mkpa ga-eyi mkpuchi uzuzu, na ịdị elu nke ọdịda efu ekwesịghị ịbụ ihe karịrị 0,5 mita.Dina akwa akwa igwe anaghị agba nchara n'elu akwa akwa akwa, wee tinye bọọlụ seramiiki (Ø10 ~ 15mm) nke nwere ọkpụrụkpụ 10 ~ 15cm.

Ihe na-akpata anaghị achọ ọgwụgwọ mbelata tupu ejiri ya.

Mbupu, ngwugwu na nchekwa

A) Xintan nwere ike ibuga ibu n'okpuru 5000kgs n'ime ụbọchị 7.
B) 1kg n'ime ngwugwu agụụ.
C) Debe ya ka ọ kpọọ nkụ ma mechie drum ígwè mgbe ị na-echekwa ya.

CO2
CO1

Ngwa nke ihe na-ewepu CO

A na-eji ya maka CO na H2 na-ewepụ na CO2, Ọ nwere ike ịtụgharị CO n'ime CO2 site na oxidation ma gbanwee H2 n'ime H2O Ngwa bụ nchekwa na ike n'efu.


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